April 1, 2023
Er, Yb: phosphate glass

What is an Er, Yb: phosphate glass?

The glass doped with Er and also ytterbium ions is Er glass; Glasses doped with erbium, ytterbium, and chromium ions are also erbium glasses; the double adhered crystal of erbium glass as well as white glass is also erbium glass. This paper mainly presents Er, Yb doped glass. The glass substrate concerned is not common glass yet phosphate glass.

Er3+, Yb3+ co-doped phosphate glass (Er, Yb: phosphate glass) is a preferred and also generally made use of energetic device for lasers creating in the “eye-safe” spooky collection of 1,5-1,6 ┬Ám.

What is phosphate glass?

Phosphate glass is a glass product that primarily consists of phosphorus pentoxide (P2O5) and typically also includes other chemical elements. It can be utilized as a laser gain tool wholesale and also fiber. Its main advantage is its high compatibility with rare-earth ions (see rare-earth-doped gain media), such as Erbium (Er3+), ytterbium (Yb3+), and neodymium (Nd3+) ions.

To put it simply, the phosphate glass varieties can be doped with a high concentration of laser-active uncommon planet ions without causing damaging impacts such as clustering, which will certainly produce a quenching result as well as influence the efficiency of the laser. The doping concentration in phosphate erbium-doped fiber is a lot more than that in quartz fiber, and also it can boost by numerous portion points. The high doping concentration of phosphate enables brief fiber lasers and amplifiers, which are not the only benefits of the glass but likewise include:

  • The brief fiber laser resonator can obtain a large totally free spectrum range, making it easier to attain single-frequency operation.
  • Distributed comments lasers are brief, whereas highly drugged phosphate fibers permit much more efficient pump absorption.
  • Ultrashort pulsed fiber lasers are much less prone to nonlinear results if they use shorter fibers.

Er, Yb: phosphate glass

What’s the system of erbium glass?

Phosphate glass incorporates a lengthy life time (~ 8 ms) of 4I13/2 Er3+ top laser level with a reduced (2-3 ms) lifetime of 4I11/2 Er3+ level that remains to remain in vibration with Yb3+ 2F5/2 fired up state. Quick non-radiative multi-phonon recreation from 4I11/2 to 4I13/2 level considerably minimizes the back-energy transfer as well as up-conversion losses as a result of the interaction between Yb3+ as well as Er3+ ions, thrilled at the 2F5/2 along with the 4I11/2 levels, specifically.

Basically continually, erbium-ytterbium-doped phosphate glass is pumped with wavelengths around the 975-nm absorption elevation of Yb3+ ions. That results in the excitation of the ytterbium ions. Later, Yb ions may transfer the excitation power to bordering erbium ions. After an efficient power transfer, one preliminary has an Er3+ ion in the 4I11/2 state (even more especially, a Stark level manifold), which has similar excitation energy as the Yb3+ ions.

From that state, the ions generally go through a fast non-radiative shift to the state 4I13/2, regularly made use of as the leading laser degree. Such non-radiative changes occur based upon multi-phonon discharge, provided that the phonon power of the product is high and also adequate (which holds for silica fibers, for example).

Application of Er, Yb: glass in Erbium glass laser

  • Er, glass is additionally a remarkable item for upconversion luminescence. Laser acquired the environment-friendly and red laser from erbium-doped glass fiber, as well as people also observed violet upconversion light. The upconversion luminescence of Er: phosphate glass thrilled by Nd: YAG was discovered. The upconversion laser will absolutely be truly practical in lots of applications.
  • Er, glass is a pure three-level laser tool. As a result of this, it needs to pump nearly all the energised glass aspects. The non-pumped locations give laser light absorption losses. When it comes to the conventional post arrangement, the non-pumped pole needs to be as short as possible.
  • The optical excitation of the Yb, Er glasses (specifically chromium-free ones) happens primarily utilizing Yb ions. The only Yb absorption band hinges on the near-infrared spectral variety (900– 1000 nm). Water termination in this spooky variety is 1 cm-1. Because of this, Er glass can significantly reduce the water-cooled laser performance due to pump light absorption in the water layer surrounding the flashlamp as well as the laser rod.

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